Early Cretaceous U–Pb zircon ages for the Copiapó plutonic complex and implications for the IOCG mineralization at Candelaria, Atacama Region, Chile     

Robert Marschik  Frank Söllner 《Mineralium Deposita》2006,41(8):785-801

Four of the major plutons in the vicinity of the Candelaria mine (470 Mt at 0.95% Cu, 0.22 g/t Au, 3.1 g/t Ag) and a dike–sill system exposed in the Candelaria open pit have been dated with the U–Pb zircon method. The new geochronological data indicate that dacite magmatism around 123 Ma preceded the crystallization of hornblende diorite (Khd) at 118 ± 1 Ma, quartz–monzonite porphyry (Kqm) at 116.3 ± 0.4 Ma, monzodiorite (Kmd) at 115.5 ± 0.4 Ma, and tonalite (Kt) at 110.7 ± 0.4 Ma. The new ages of the plutons are consistent with field relationships regarding the relative timing of emplacement. Plutonism temporally overlaps with the iron oxide Cu–Au mineralization (Re–Os molybdenite ages at ∼115 Ma) and silicate alteration (ages mainly from 114 to 116 and 110 to 112 Ma) in the Candelaria–Punta del Cobre district. The dated dacite porphyry and hornblende diorite intrusions preceded the ore formation. A genetic link of the metallic mineralization with the quartz–monzonite porphyry and/or the monzodiorite is likely. Both of these metaluminous, shoshonitic (high-K) intrusions could have provided energy and contributed fluids, metals, and sulfur to the hydrothermal system that caused the iron oxide Cu–Au mineralization. The age of the tonalite at 110.7 Ma falls in the same range as the late alteration at 110 to 112 Ma. Tonalite emplacement may have sustained existing or driven newly developed hydrothermal cells that caused this late alteration or modified ⁴⁰Ar/³⁹Ar and K/Ar systematic in some areas.  相似文献   

Petrology, geochemistry and the mechanisms determining the distribution of platinum-group element and base metal sulphide mineralisation in the Platreef at Overysel, northern Bushveld Complex, South Africa     

David A. Holwell  Iain McDonald 《Mineralium Deposita》2006,41(6):575-598

Platinum-group element (PGE) mineralisation within the Platreef at Overysel is controlled by the presence of base metal sulphides (BMS). The floor rocks at Overysel are Archean basement gneisses, and unlike other localities along the strike of the Platreef where the floor is comprised of Transvaal Supergroup sediments, the intimate PGE–BMS relationship holds strong into the footwall rocks. Decoupling of PGE from BMS is rare and the BMS and platinum-group mineral assemblages in the Platreef and the footwall are almost identical. There is minimal overprinting by hydrothermal fluids; therefore, the mineralisation style present at Overysel may represent the most ‘primary’ style of Platreef mineralisation preserved anywhere along the strike. Chondrite-normalised PGE profiles reveal a progressive fractionation of the PGE with depth into the footwall, with Ir, Ru and Rh dramatically depleted with depth compared to Pt, Pd and Au. This feature is not observed at Sandsloot and Zwartfontein, to the south of Overysel, where the footwall rocks are carbonates. There is evidence from rare earth element abundances and the amount of interstitial quartz towards the base of the Platreef pyroxenites that contamination by a felsic melt derived from partial melting of the gneissic footwall has taken place. Textural evidence in the gneisses suggests that a sulphide liquid percolated down into the footwall through a permeable, inter-granular network that was produced by partial melting around grain boundaries in the gneisses that was induced by the intrusion of the Platreef magma. PGE were originally concentrated within a sulphide liquid in the Platreef magma, and the crystallisation of monosulphide solid solution from the sulphide liquid removed the majority of the IPGE and Rh from it whilst still within the mafic Platreef. Transport of PGE into the gneisses, via downward migration of the residual sulphide liquid, fractionated out the remaining IPGE and Rh in the upper parts of the gneisses leaving a ‘slick’ of disseminated sulphides in the gneiss, with the residual liquid becoming progressively more depleted in these elements relative to Pt, Pd and Au. Highly sulphide-rich zones with massive sulphides formed where ponding of the sulphide liquid occurred due to permeability contrasts in the footwall. This study highlights the fact that there is a fundamental floor rock control on the mechanism of distribution of PGE from the Platreef into the footwall rocks. Where the floor rocks are sediments, fluid activity related to metamorphism, assimilation and later serpentinisation has decoupled PGE from BMS in places, and transport of PGE into the footwall is via hydrothermal fluids. In contrast, where the floor is comprised of anhydrous gneiss, such as at Overysel, there is limited fluid activity and PGE behaviour is controlled by the behaviour of sulphide liquids, producing an intimate PGE–BMS association. Xenoliths and irregular bands of chromitite within the Platreef are described in detail for the first time. These are rich in the IPGE and Rh, and evidence from laurite inclusions indicates they must have crystallised from a PGE-saturated magma. The disturbed and xenolithic nature of the chromitites would suggest they are rip-up clasts, either disturbed by later pulses of Platreef magma in a multi-phase emplacement or transported into the Platreef from a pre-existing source in a deeper staging chamber or conduit.  相似文献   

The Removal of Dissolved Metals by Hydroxysulphate Precipitates during Oxidation and Neutralization of Acid Mine Waters, Iberian Pyrite Belt   总被引：4，自引：0，他引：4  

J. Sánchez España  E. López Pamo  E. Santofimia Pastor  J. Reyes Andrés  J. A. Martín Rubí 《Aquatic Geochemistry》2006,12(3):269-298

This study examines the removal of dissolved metals during the oxidation and neutralization of five acid mine drainage (AMD) waters from La Zarza, Lomero, Esperanza, Corta Atalaya and Poderosa mines (Iberian Pyrite Belt, Huelva, Spain). These waters were selected to cover the spectrum of pH (2.2–3.5) and chemical composition (e.g., 319–2,103 mg/L Fe; 2.85–33.3 g/L SO₄⁼) of the IPB mine waters. The experiments were conducted in the laboratory to simulate the geochemical evolution previously recognized in the field. This evolution includes two stages: (1) oxidation of dissolved Fe(II) followed by hydrolysis and precipitation of Fe(III), and (2) progressive pH increase during mixing with fresh waters. Fe(III) precipitates at pH < 3.5 (stages 1 and 2) in the form of schwertmannite, whereas Al precipitates during stage 2 at pH 5.0 in the form of several hydroxysulphates of variable composition (hydrobasaluminite, basaluminite, aluminite). During these stages, trace elements are totally or partially sorbed and/or coprecipitated at different rates depending basically on pH, as well as on the activity of the SO₄⁼ anion (which determines the speciation of metals). The general trend for the metals which are chiefly present as aqueous free cations (Pb²⁺, Zn²⁺, Cu²⁺, Cd²⁺, Mn²⁺, Co²⁺, Ni²⁺) is a progressive sorption at increasing pH. On the other hand, As and V (mainly present as anionic species) are completely scavenged during the oxidation stage at pH < 3.5. In waters with high activities (> 10⁻¹) of the SO ₄⁼ ion, some elements like Al, Zn, Cd, Pb and U can also form anionic bisulphate complexes and be significantly sorbed at pH < 5. The removal rates at pH 7.0 range from around 100% for As, V, Cu and U, and 60–80% for Pb, to less than 20% for Zn, Co, Ni and Mn. These processes of metal removal represent a significant mechanism of natural attenuation in the IPB.  相似文献   

贵州钼矿地质特征及找矿前景   总被引：5，自引：0，他引：5  

樊正烈 《贵州地质》2006,23(2):103-108

通过对贵州钼矿床(点)的产出层位、区域分布、成因类型、典型矿床地质特征及各类型矿床的矿石结构、构造和品位情况的初步综合分析,进一步对寻找钼矿床指出了方向。  相似文献   

理想点法在矿床工业价值评价中的应用     

王睿  张立新 《贵州地质》2006,23(4):282-285

应用理想点法的基本原理,建立了一个矿床工业价值评价的数学模型,以我国贵州省兴义市雄武地区铀矿床为实例,构造评价函数得出最优解,结果表明:理想点法能够正确评价出矿床工业价值的大小,为矿石的最优开采提供有价值的参考。  相似文献   

鄂尔多斯盆地北部底河道砂岩型铀矿地质特征   总被引：3，自引：0，他引：3  

吴仁贵  祝民强  余达淦  周万蓬 《华东地质学院学报》2006,29(1):1-6

鄂尔多斯盆地北部直罗组中的铀矿,是典型的产于河道中的砂岩铀矿,该矿床发育较好的卷状矿体。通过对该铀矿地质特征的研究,认识到发育卷状矿体的底河道砂岩型铀矿必须具备两大条件:其一是成矿砂体条件,即砂体要有较好的成层性、连通性和渗透性;其二是地层结构条件,即砂体必须存在较好的上、下隔水岩层。就砂体而言,河流相辫状沉积砂体是形成卷状矿体的主要砂体,并且以具有从辫状河向曲流河完整演化的辫状沉积砂体较好。砂体的上、下隔水岩层则有多种表现形式:下隔水层可由不透水的基岩或湖相沉积泥岩等构成;上隔水层由不透水的湖相泥岩、曲流沉积地层或岩浆岩等构成。在层间氧化作用过程上,存在纵横两个方向的氧化,即存在与河道方向一致的纵向氧化和与河道垂直的横向氧化,两种氧化作用成矿常叠加形成复杂的矿体类型;在矿化赋存的部位上,铀砂体通常发育在基底之上或不同建造之间;在古气候演变上,成矿作用发生在干旱气候条件下,或由潮湿向干旱的气候转变阶段。  相似文献   

探测地雷技术研究综述     

WANG Shi-yu FENG Zhi-hui College of GeoExploration Science  Technology  Jilin University  Changchun  China 《吉林大学学报(地球科学版)》2006,(Z2)

高敏感度、高可靠度、低花费传感器是全自动或半自动探雷机器人的首要和绝对的选择。当前,有许多技术能够被选来综合使用以满足上述的要求。金属探测器是一种传统的、成熟可靠的探测技术。但是,现在多种地雷含有少量的金属或者不包含任何金属,造成了用金属探测器探雷的困难。目前迫切需要研究发展新颖的探测技术以消除100万颗地雷对许多国家的影响。  相似文献   

藏南地区金和锑矿床(点)类型及其时空分布特征   总被引：37，自引：5，他引：37       下载免费PDF全文

聂凤军  胡朋  江思宏  李振清  刘妍  周永章 《地质学报》2005,79(3):373-385

本文首次对藏南地区金和锑矿床(点)地质特征、成因类型和空间分布特点进行了总结，对金和锑成矿作用与中新生代构造一岩浆活动的关系进行了论证，对区域地壳演化过程中金和锑成矿动力学机制进行了讨论。该区的金和锑矿床(点)可按容矿围岩划分为：①变质岩为主要容矿围岩矿床(点)，包括金和金一锑矿床(点)；②沉积岩为主要容矿围岩矿床(点)，包括金、锑、金一锑和锑多金属矿床(点)；③火山岩为主要容矿围岩矿床(点)，以金一银矿床为代表。根据金和锑矿床(点)空间分布特点和地质特点，将本区划分为4个矿化集中区：拉昂错一马攸木一帕羊金矿化集中区(A)，然勒金和锑矿化集中区(B)，洛扎一措美锑矿化集中区(C)和邛多江金一锑矿化集中区(D)。各矿化集中区内大多数金和锑矿床(点)与燕山晚期～喜马拉雅早期富碱火成岩具密切时空分布关系，它们是古板块对接碰撞期和碰撞期后大规模构造一岩浆活动的产物。近东西向挤压性和南北向张性断裂交汇部位以及富碱火成岩发育区是寻找金和锑矿床(点)的有利场所。  相似文献   

四川昌台农都柯金银矿矿床地质特征及成矿远景     

许远平  姚丽  李继军 《物探化探计算技术》2005,27(3):241-245

农都柯火山岩浅成低温热液型金银矿床系在三江地区义敦岛弧带被首次发现,经初步评价达到中型规模。矿床赋存于流纹质火山碎屑岩中,受北北西向剪切带控制,矿体呈透镜状或似层状,基本顺层产出。围岩蚀变强烈,以硅化为主,次为绢云母化和重晶石化。矿石由黄铁矿、闪锌矿、自然金、辉锑铅矿、砷黝铜矿、辉锑矿、辉锑银铅矿、雄黄、雌黄等组成,为典型的低温热液矿物组合。主矿化温度发生在200℃以下,矿化元素除Ag、Au外,As、Sb、Hg也达到或接近工业品位。通过地球物理、地球化学方法的测量,成矿远景较好。  相似文献   

新疆卡拉麦里金矿带成矿规律及找矿预测   总被引：2，自引：0，他引：2  

薄科武  杨向东  曾长华 《新疆地质》2005,23(2):131-135

新疆卡拉麦里成矿带内地层较全、构造发育、岩浆活动频繁，志留系、泥盆系和石炭系在带内广泛发育，为本区主要含金地层．卡拉麦里深断裂严格控制区内侵入岩、次一级构造和矿产分布，构成岩浆侵入的主要通道，与此有关的次一级断层和裂隙则构成良好的赋存空间．卡拉麦里深大断裂纵贯全区，金成矿地质条件优越，沿走向Au异常、金矿床(点)成群成带分布，最后确定了7个金找矿远景区．  相似文献